Best overlap: 1:00 PM to 6:00 PM in Cape Town is 8:00 AM to 1:00 PM in Brasília.
Plan around 1:00 PM to 6:00 PM in Cape Town, which is 8:00 AM to 1:00 PM in Brasília, to catch everyone during office hours. Since Brasília is 5 hours behind Cape Town, the workdays overlap by around 5 hours; 1:00 PM in Cape Town (8:00 AM in Brasília) makes a reliable recurring slot.
24/7 support sounds great until a P1 ticket falls into the gap between Manila signing off and Dublin signing on. Here is how to design a follow-the-sun support model that actually catches tickets at the boundary. -